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Photocatalytic reduction of organic pollutant under visible light by green route synthesized gold na
閱讀：202 發(fā)布時間：2017-8-231 School of Chemical Sciences, North Maharashtra University, Jalgaon 425001, Maharashtra, India
2 Centre for Environmental Science & Engineering, Indian Institute of Technology Kanpur, Kanpur 208016, Uttar Pradesh, India
3 Department of Earth Sciences, Indian Institute of Technology Kanpur, Kanpur 208016, Uttar Pradesh, India
4 Environmental Engineering and Management, Department of Civil Engineering, Indian Institute of Technology Kanpur, Kanpur 208016, Uttar Pradesh, India
5 Directorate of Geology and Mining, Government of Maharashtra, Nagpur 440010, Maharashtra, India
摘要：We report a rapid method of green chemistry approach for synthesis of gold nanoparticles (AuNPs) using Lagerstroemia speciosa leaf extract (LSE). L. speciosa plant extract is known for its effective treatment of diabetes and kidney related problems. The green synthesis of AuNPs was complete within 30 min at 25°C. The same could also be achieved within 2 min at a higher reaction temperature (80°C). Both UV–visible spectroscopy and transmission electron microscopy results suggest that the morphology and size distribution of AuNPs are dependent on the pH of gold solution, gold concentration, volume of LSE, and reaction time and temperature. Comparison between Fourier transform infrared spectroscopy (FT-IR) spectra of LSE and the synthesized AuNPs indicate an active role of polyphenolic functional groups (from gallotannins, lagerstroemin, and corosolic acid) in the green synthesis and capping of AuNPs. The green route synthesized AuNPs show strong photocatalytic activity in the reduction of dyes viz., methylene blue, methyl orange, bromophenol blue and bromocresol green, and 4-nitrophenol under visible light in the presence of NaBH4. The non-toxic and cost effective LSE mediated AuNPs synthesis proposed in this study is extremely rapid compared to the other reported methods that require hours to days for complete synthesis of AuNPs using various plant extracts. Strong and stable photocatalytic behavior makes AuNPs attractive in environmental applications, particularly in the reduction of organic pollutants in wastewater.